Molecules/Elements/Particles

 

Wednesday
Oct172012

Niobium

"Niobium (play /nˈbiəm/ny-oh-bee-əm or columbium (/kəˈlʌmbiəm/ kə-lum-bee-əm), is a chemical element with the symbol Nb and atomic number41. It is a soft, grey, ductile transition metal, which is often found in the pyrochlore mineral, the main commercial source for niobium, and columbite. The name comes from Greek mythologyNiobe, daughter of Tantalus."

"Niobium has physical and chemical properties similar to those of the element tantalum, and the two are therefore difficult to distinguish. The English chemist Charles Hatchett reported a new element similar to tantalum in 1801 and named it columbium. In 1809, the English chemist William Hyde Wollaston wrongly concluded that tantalum and columbium were identical. The German chemist Heinrich Rose determined in 1846 that tantalum ores contain a second element, which he named niobium. In 1864 and 1865, a series of scientific findings clarified that niobium and columbium were the same element (as distinguished from tantalum), and for a century both names were used interchangeably. The name of the element was officially adopted as niobium in 1949."

"It was not until the early 20th century that niobium was first used commercially. Brazil is the leading producer of niobium and ferroniobium, an alloyof niobium and iron. Niobium is used mostly in alloys, the largest part in special steel such as that used in gas pipelines. Although alloys contain only a maximum of 0.1%, that small percentage of niobium improves the strength of the steel. The temperature stability of niobium-containing superalloys is important for its use in jet and rocket engines. Niobium is used in various superconducting materials. These superconducting alloys, also containing titanium and tin, are widely used in the superconducting magnets of MRI scanners. Other applications of niobium include its use in welding, nuclear industries, electronics, optics, numismatics and jewelry. In the last two applications, niobium's low toxicity and ability to be colored by anodization are particular advantages."

Monday
Oct152012

Actinium

"Actinium (play /ækˈtɪniəm/ ak-tin-nee-əm) is a radioactive chemical element with symbol Ac (not to be confused with the abbreviation for an acetyl group) and has the atomic number 89, which was discovered in 1899. It was the first non-primordial radioactive element to be isolated. Polonium,radium and radon were observed before actinium, but they were not isolated until 1902. Actinium gave the name to the actinide series, a group of 15 similar elements between actinium and lawrencium in the periodic table."

"A soft, silvery-white radioactive metal, actinium reacts rapidly with oxygen and moisture in air forming a white coating of actinium oxide that prevents further oxidation. As with most lanthanides and actinides, actinium assumes oxidation state +3 in nearly all its chemical compounds. Actinium is found only in traces in uranium ores as the isotope 227Ac, which decays with a half-life of 21.772 years, predominantly emitting beta particles. One tonne of uranium ore contains about 0.2 milligrams of actinium. The close similarity of physical and chemical properties of actinium and lanthanum makes separation of actinium from the ore impractical. Instead, the element is prepared, in milligram amounts, by the neutron irradiation of 226Ra in a nuclear reactor. Owing to its scarcity, high price and radioactivity, actinium has no significant industrial use. Its current applications include a neutron source and an agent for radiation therapy targeting cancer cells in the body."

Friday
Oct122012

Cadmium

"Cadmium (play /ˈkædmiəm/ kad-mee-əm) is a chemical element with the symbol Cd and atomic number 48. This soft, bluish-white metal is chemically similar to the two other stable metals in group 12zinc and mercury. Like zinc, it prefers oxidation state +2 in most of its compounds and like mercury it shows a low melting point compared to transition metals. Cadmium and its congeners are not always considered transition metals, in that they do not have partly filled d or f electron shells in the elemental or common oxidation states. The average concentration of cadmium in the Earth's crust is between 0.1 and 0.5 parts per million (ppm). It was discovered in 1817 simultaneously by Stromeyer and Hermann, both in Germany, as an impurity in zinc carbonate."

"Cadmium occurs as a minor component in most zinc ores and therefore is a byproduct of zinc production. It was used for a long time as a pigment and for corrosion resistant plating on steel while cadmium compounds were used to stabilize plastic. With the exception of its use in nickel–cadmium batteries and cadmium telluride solar panels, the use of cadmium is generally decreasing. These declines have been due to competing technologies, cadmium’s toxicity in certain forms and concentration and resulting regulations.[2] Although cadmium has no known biological function in higher organisms, a cadmium-dependent carbonic anhydrase has been found in marine diatoms."

Thursday
Oct112012

Selenium

"Selenium (/sɨˈlniəm/ sə-lee-nee-əm) is a chemical element with symbol Se and atomic number 34. It is a nonmetal with properties that are intermediate between those of its periodic table column-adjacent chalcogen elements sulfur and tellurium. It rarely occurs in its elemental state in nature, or as pure ore compounds. Selenium (Greek σελήνη selene meaning "Moon") was discovered in 1817 by Jöns Jakob Berzelius, who noted the similarity of the new element to the previously-known tellurium (named for the Earth)."

"Selenium is found impurely in metal sulfide ores, where it partially replaces the sulfur. Commercially, selenium is produced as a byproduct in the refining of these ores, most often during copper production. Minerals that are pure selenide or selenate compounds are known, but are rare. The chief commercial uses for selenium today are in glassmaking and in pigments. Selenium is a semiconductor and is used in photocells. Uses inelectronics, once important, have been mostly supplanted by silicon semiconductor devices. Selenium continues to be used in a few types of DC power surge protectors and one type of fluorescent quantum dot."

Monday
Oct082012

Erbium

"Erbium (play /ˈɜrbiəm/) is a chemical element in the lanthanide series, with the symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements on Earth. As such, it is a rare earth element which is associated with several other rare elements in the mineral gadolinite from Ytterby in Sweden."

"Erbium's principal uses involve its pink-colored Er3+ ions, which have optical fluorescent properties particularly useful in certain laser applications. Erbium-doped glasses or crystals can be used as optical amplification media, where erbium (III) ions are optically pumped at around 980 nm or 1480 nm and then radiate light at 1530 nm in stimulated emission. This process results in an unusually mechanically simple laser optical amplifier for signals transmitted by fiber optics. The 1550 nm wavelength is especially important for optical communications because standard single mode optical fibers have minimal loss at this particular wavelength. In addition to optical fiber lasers, a large variety of medical applications (i.e. dermatology, dentistry) utilize the erbium ion's 2940 nm emission (see Er:YAG laser), which is highly absorbed in water in tissues, making its effect very superficial. Such shallow tissue deposition of laser energy is helpful in laser surgery, and for the efficient production of steam for laser enamel ablation in certain types of laser dentistry."

Saturday
Oct062012

Scandium

"Scandium (play /ˈskændiəm/ skan-dee-əm) is a chemical element with symbol Sc and atomic number 21. A silvery-white metallic transition metal, it has historically been sometimes classified as a rare earth element, together with yttrium and the lanthanoids. It was discovered in 1879 by spectral analysis of the minerals euxenite and gadolinite from Scandinavia."

"Scandium is present in most of the deposits of rare earth and uranium compounds, but it is extracted from these ores in only a few mines worldwide. Because of the low availability and the difficulties in the preparation of metallic scandium, which was first done in 1937, it took until the 1970s before applications for scandium were developed. The positive effects of scandium on aluminium alloys were discovered in the 1970s, and its use in such alloys remains its only major application."

"The properties of scandium compounds are intermediate between those of aluminium and yttrium. A diagonal relationship exists between the behavior of magnesium and scandium, just as there is between beryllium and aluminium. In the chemical compounds of the elements shown as group 3, above, the predominant oxidation state is +3."

Friday
Oct052012

Molybdenum

"Molybdenum (play /ˌmɒlɪbˈdnəm/ mol-ib-dee-nəm or /məˈlɪbdɨnəm/ mə-lib-di-nəm), is a Group 6 chemical element with the symbol Mo and atomic number 42. The name is from Neo-Latin Molybdaenum, from Ancient Greek Μόλυβδος molybdos, meaning lead, since its ores were confused with lead ores.[4] Molybdenum minerals have been known into prehistory, but the element was "discovered" (in the sense of differentiating it as a new entity from the mineral salts of other metals) in 1778 by Carl Wilhelm Scheele. The metal was first isolated in 1781 by Peter Jacob Hjelm."

"Molybdenum does not occur naturally as a free metal on Earth, but rather in various oxidation states in minerals. The free element, which is a silvery metal with a gray cast, has the sixth-highest melting point of any element. It readily forms hard, stable carbides in alloys, and for this reason most of world production of the element (about 80%) is in making many types of steel alloys, including high strength alloys and superalloys."

"Most molybdenum compounds have low solubility in water, but the molybdate ion MoO42− is soluble and forms when molybdenum-containing minerals are in contact with oxygen and water. Industrially, molybdenum compounds (about 14% of world production of the element) are used inhigh-pressure and high-temperature applications, as pigments and catalysts."

Wednesday
Oct032012

Infrared

"Infrared (IR) light is electromagnetic radiation with longer wavelengths than those of visible light, extending from the nominal red edge of the visible spectrum at 0.74 micrometres (µm) to 300 µm. This range of wavelengths corresponds to a frequency range of approximately 1 to 400 THz,[1] and includes most of the thermal radiation emitted by objects near room temperature. IR light is emitted or absorbed by molecules when they change their rotational-vibrational movements. The existence of IR radiation was first discovered in 1800 by astronomer William Herschel."

"Much of the energy from the Sun arrives on Earth in the form of IR radiation. Sunlight at zenith provides an irradiance of just over 1 kilowatt per square meter at sea level. Of this energy, 527 watts is IR radiation, 445 watts is visible light, and 32 watts is ultraviolet radiation.[2] The balance between absorbed and emitted IR radiation has a critical effect on the Earth's climate."

"IR light is used in industrial, scientific, and medical applications. Night-vision devices using IR illumination allow people or animals to be observed without the observer being detected. In astronomy, imaging at IR wavelengths allows observation of objects obscured by interstellar dust. IR imaging cameras are used to detect heat loss in insulated systems, to observe changing blood flow in the skin, and to detect overheating of electrical apparatus."

Monday
Oct012012

Germanium

"Germanium (play /ərˈmniəm/ jər-may-nee-əm) is a chemical element with symbol Ge and atomic number 32. It is a lustrous, hard, grayish-whitemetalloid in the carbon group, chemically similar to its group neighbors tin and silicon. Purified germanium is a semiconductor, with an appearance most similar to elemental silicon. Like silicon, germanium naturally reacts and forms complexes with oxygen in nature. Unlike silicon, it is too reactive to be found naturally on Earth in the free (native) state."

"Because very few minerals contain it in high concentration, germanium was discovered comparatively late in the history of chemistry. Germanium ranks near fiftieth in relative abundance of the elements in the Earth's crust. In 1869, Dmitri Mendeleev predicted its existence and some of its properties based on its position on his periodic table and called the element ekasilicon. Nearly two decades later, in 1886, Clemens Winkler found the new element along with silver and sulfur, in a rare mineral called argyrodite. Although the new element somewhat resembled arsenic and antimony in appearance, its combining ratios in the new element's compounds agreed with Mendeleev's predictions for a predicted relative of silicon. Winkler named the element after his country, Germany. Today, germanium is mined primarily from sphalerite (the primary ore of zinc), though germanium is also recovered commercially from silverlead, and copper ores."

Friday
Sep282012

Seaborgium

"Seaborgium (Listeni/sˈbɔrɡiəm/ see-bor-gee-əm) is a synthetic chemical element with the symbol Sg and atomic number 106."

"Seaborgium is a synthetic element whose most stable isotope 271Sg has a half-life of 1.9 minutes. A new isotope 269Sg has a potentially slightly longer half-life (ca. 2.1 min) based on the observation of a single decay.[citation needed] Chemistry experiments with seaborgium have firmly placed it in group 6 as a heavier homologue to tungsten."

"Element 106, now known as seaborgium, was first created in 1974 at the Super HILAC accelerator at the Lawrence Berkeley Laboratory by a joint Lawrence Berkeley/Lawrence Livermore collaboration led by Albert Ghiorso and E. Kenneth Hulet.[2] They produced the new nuclide 263Sg by bombarding a target of 249Cf with 18O ions. This nuclide decays by α emission with a half-life of 0.9 ± 0.2 sec."

"Seaborgium is projected to be the third member of the 6d series of transition metals and the heaviest member of group 6 in the Periodic Table, belowchromiummolybdenum and tungsten. All the members of the group readily portray their group oxidation state of +6 and the state becomes more stable as the group is descended. Thus seaborgium is expected to form a stable +6 state. For this group, stable +5 and +4 states are well represented for the heavier members and the +3 state is known but reducing, except for chromium(III)."

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